Acetic Acid Solution Safety Data Sheet (SDS)
This Safety Data Sheet (SDS) provides information on the hazards of acetic acid solution and how to handle it safely. Acetic acid solution is a common laboratory chemical and industrial reagent used in various applications.
1. Identification
- Product Name: Acetic Acid Solution
- Synonyms: Glacial Acetic Acid, Ethanoic Acid, Vinegar Acid
- CAS Number: 64-19-7
- Manufacturer/Supplier: [Your company name and address]
2. Hazards Identification
GHS Classification
- Skin Corrosion/Irritation: Category 1B
- Serious Eye Damage/Eye Irritation: Category 1B
- Respiratory Sensitizer: Category 1
- Specific Target Organ Toxicity - Single Exposure: Category 3 (Respiratory Tract irritation)
Hazard Statements
- H314: Causes severe skin burns and eye damage.
- H334: May cause allergy or asthma symptoms or respiratory irritation.
- H335: May cause respiratory irritation.
Precautionary Statements
- P260: Do not breathe dust/fume/gas/mist/vapors/spray.
- P280: Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.
- P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
- P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P312: Call a POISON CENTER or doctor if you feel unwell.
- P332+P313: If skin irritation occurs: Get medical advice/attention.
- P405: Store locked up.
3. Composition/Information on Ingredients
- Acetic Acid: ≥ 99%
4. First-Aid Measures
- Inhalation: Remove victim to fresh air. If breathing is difficult, administer oxygen. If unconscious, give artificial respiration. Get medical attention immediately.
- Skin Contact: Immediately remove contaminated clothing and shoes. Flush affected area with plenty of water for at least 15 minutes. Remove contaminated clothing. Get medical attention immediately.
- Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Remove contact lenses if they are present and easy to do. Get medical attention immediately.
- Ingestion: Do not induce vomiting. Give large amounts of water. Get medical attention immediately.
5. Fire-Fighting Measures
- Suitable Extinguishing Media: Water spray, dry chemical, carbon dioxide, foam.
- Unsuitable Extinguishing Media: Do not use direct water jet on fire.
- Specific Hazards Arising from the Chemical: Acetic acid is flammable and can produce irritating and corrosive fumes when heated.
- Special Protective Equipment and Precautions for Fire Fighters: Wear self-contained breathing apparatus and full protective clothing.
6. Accidental Release Measures
- Personal Precautions: Evacuate personnel from the area. Ensure adequate ventilation. Wear appropriate personal protective equipment.
- Environmental Precautions: Prevent entry into drains, sewers, or watercourses.
- Methods and Materials for Containment and Cleaning Up: Contain spill with absorbent material (sand, vermiculite, etc.). Transfer to a suitable container for disposal. Flush area with plenty of water.
7. Handling and Storage
- Handling: Avoid contact with skin, eyes, and clothing. Use only in well-ventilated areas. Do not breathe vapors.
- Storage: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep container tightly closed.
8. Exposure Controls/Personal Protection
- Engineering Controls: Use local exhaust ventilation at the source of the exposure.
- Personal Protective Equipment:
- Respiratory Protection: Wear a respirator with an organic vapor cartridge when handling acetic acid.
- Eye Protection: Wear chemical splash goggles.
- Skin Protection: Wear chemical-resistant gloves (e.g., nitrile, neoprene) and protective clothing.
- Other Protective Equipment: Wear appropriate safety shoes.
9. Physical and Chemical Properties
- Appearance: Clear, colorless liquid
- Odor: Pungent, vinegary odor
- pH: 2.4 (10% solution)
- Boiling Point: 118°C (244°F)
- Melting Point: 17°C (63°F)
- Flash Point: 39°C (102°F)
- Solubility: Miscible with water, ethanol, and ether.
10. Stability and Reactivity
- Stability: Stable under normal conditions.
- Conditions to Avoid: Heat, open flame, strong oxidizing agents.
- Incompatibility: Strong bases, oxidizing agents.
- Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acetic anhydride.
11. Toxicological Information
- Acute Toxicity: Acetic acid is corrosive to skin, eyes, and mucous membranes. Ingestion can cause severe burns of the mouth, throat, and stomach. Inhalation of vapors can cause irritation of the respiratory tract.
- Skin Corrosion/Irritation: Causes severe skin burns.
- Serious Eye Damage/Eye Irritation: Causes severe eye burns.
- Respiratory Sensitizer: May cause allergy or asthma symptoms or respiratory irritation.
- Specific Target Organ Toxicity - Single Exposure: May cause respiratory irritation.
12. Ecological Information
- Ecotoxicity: Acetic acid is harmful to aquatic organisms.
- Persistence and Degradability: Acetic acid is readily biodegradable.
- Bioaccumulation Potential: Acetic acid does not bioaccumulate.
- Mobility in Soil: Acetic acid is mobile in soil.
13. Disposal Considerations
- Waste Disposal Methods: Dispose of in accordance with local regulations.
14. Transport Information
- UN Number: UN2789
- Proper Shipping Name: Acetic Acid, solution
- Hazard Class: 8 (Corrosive)
- Packing Group: II
15. Regulatory Information
- This product is subject to various local, state, and federal regulations. Consult the relevant regulations for specific requirements.
16. Other Information
- Date of Issue: [Date]
- Revision Date: [Date]
- Prepared by: [Your company name]
Disclaimer: This SDS is provided for informational purposes only and should not be considered as a substitute for professional advice. Users are responsible for ensuring compliance with all applicable safety and regulatory requirements.
